As makerspaces and fab labs increase in popularity, more and more libraries are adding 3D-printing capabilities. According to a 2015 American Library Association (ALA) report, 428 public library branches have made this technology available. Some potential issues of 3D printing, such as the threat of printing weapons and copyrighted works, are often considered. However, discussion of the health hazards associated with 3D printing is rare.
Ultrafine particles and volatile organic compounds
Several studies have shown that 3D printers produce high amounts of ultrafine particles (UFPs) and volatile organic compounds (VOCs) while in use, and that these particles and vapors are detectable for many hours after the printers have been shut off. UFPs have been linked to adverse health conditions, such as asthma and cardiovascular issues, because they can pass through the lungs and travel to other organs. They can also transfer toxic material into the body, including blood and tissue cells. The US Environmental Protection Administration has classified many VOCs as toxic air pollutants. Exposure to certain VOCs, such as benzene and methylene chloride, has been linked to cancer.
UFPs and VOCs are produced by thermal decomposition when a 3D printer heats and melts a plastic filament. The most popular filaments used in 3D printing are acrylonitrile-butadiene-styrene (ABS) and polylactic-acid (PLA) filaments. Brent Stephens conducted one of the first studies on desktop 3D printer UFP and VOC emissions in 2013 in the journal Atmospheric Environment. Since then, several other studies have tested 3D printers, using both ABS and PLA filaments. Most of the studies were conducted with low-cost 3D desktop printers, the kind that libraries are most likely to purchase. The studies concluded:
- 3D printing raises the levels of UFPs dramatically in the printer’s area of operation.
- Low-cost desktop 3D printers and filaments may produce higher amounts of UFPs and VOCs than more expensive brands.
- ABS filaments produce more particle emissions than PLA filaments.
- Even with an enclosure, nonventilated 3D printers only see a small reduction in UFP emissions.
- The carcinogen styrene is produced by ABS filament heating.
- The hazardous chemical methyl methacrylate is produced by PLA filament heating.
- As a 3D printer ages it produces higher emissions of UFPs and VOCs.
All of the studies concluded that 3D printers should be placed in well-ventilated areas to limit exposure to UFPs and VOCs. Some 3D printers have built-in ventilation systems; libraries should purchase these over nonventilated, less expensive versions.
ABS and PLA food safety
The main food safety concern with 3D printers is bacterial growth due to small fissures in printed objects. Items made by 3D printers are porous, allowing bacteria to grow over time and to potentially become a health hazard. Also, children playing with 3D-printed objects run the risk of coming into contact with bacteria growing on the object after it has become soiled. Cleaning the object might prove difficult because high dishwasher temperatures can melt or warp the item (especially with PLA-printed objects). Some filaments (other than ABS and PLA) are food safe, including polyethylene terephthalate (PET), which has been FDA approved for direct food contact.
ABS-created plates, cups, and utensils can transfer dangerous chemical residues, including 1,3-butadiene, a probable human carcinogen that can cause irritation to skin and mucous membranes through contact with food. Also, UFPs and other residues from the 3D printing process could still be on the printed material. These levels are small but should still be of concern to those using 3D-printed material as dinnerware.
As new studies are conducted, we will continue to learn more about the hazards of using this technology, as well as the ways we can protect ourselves and our patrons from short- or long-term health effects. Until additional data is available, library staffers should do the following to reduce their exposure to UFPs and VOCs:
- Use 3D printers with either built-in ventilation or in well-ventilated areas.
- Keep patrons from up-close monitoring of printing activity for long periods.
- Carefully consider the risks associated with the type of plastic filament used in devices.
- Restrict patrons’ printing of items that could be used around food, such as utensils and plates.
- Follow manufacturer’s instructions.
Libraries or any public space providing or considering 3D-printing services should evaluate their space and printing policies to ensure this technology is used as safely as possible. Free safety consulting programs are available through many state workers’ compensation systems.
There is a somewhat newer study that really helps clear the air, so to speak, about 3D printers, filaments, and what they emit. IIT in Wheaton, Illinois did a comprehensive study in 2016, which you can read in its entirety here: http://pubs.acs.org/doi/pdf/10.1021/acs.est.5b04983. You can also read a slimmed down translation here: http://hackaday.com/2016/02/01/3d-printing-fumes-new-science/.
Essentially, ABS = bad, and PLA = not bad… for now, at least.
According to the 2016 Stephens study, the UFP emission rates per minute for PLA are still high: 100 million particles per minute for PLA vs. 10 billion particles per minute for ABS. I disagree with your takeaway that ABS = bad, PLA = not bad. The study seems to indicate they are both bad as far as UFPs go, but that ABS and nylon filaments have additional safety concerns related to the specific VOCs they give off.
**This is Christina, I don’t know how I logged in originally***
I understand what you’re saying, and the UFP emission rates are alarming, but if you look at the contents of the UFP, PLA emits primarily lactide, and the study given in the first link in my comment says “We are not aware of any relevant information regarding the inhalation toxicity of lactide, the primary individual VOC emitted from PLA filaments.” This is why I added the “for now” in my comment. There aren’t any current studies (at least that I am aware of) that indicate lactide is hazardous when inhaled, but there may be a revelation in the future. ABS VOCs, styrene being a large one, are malignant in nature.
I don’t want to babble, but the point of my comment was particularly emphasizing that if you have a choice in the type of filament to use in many commercially available printers, opt for PLA over ABS.